Journal of the American Chemical Society

Aromatic Fluorine Compounds. VII. Replacement of Aromatic-Cl and-NO2 Groups by-F1, 2

GC Finger, CW Kruse

文献索引：Finger; Kruse Journal of the American Chemical Society, 1956 , vol. 78, p. 6034,6037

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被引用次数: 154

摘要

Unactivated aryl halides do not undergo Swartstype organic halide-inorganic fluoride exchange reactions which are common with aliphatic and acyl haIides3s4 Activation by at least two nitro groups has generally been considered necessary for exchange between aryl halides and fluoride i0n. 5a An outstanding example of such an exchange is the replacement of chlorine by fluorine in 2, 4-dinitrochlorobenzene with anhydrous ...