A green procedure for the diazotization-iodination of aromatic amines under aqueous, strong-acid-free conditions

…, EA Krasnokutskaya, PS Postnikov, Y Choi, KW Chi…

文献索引：Trusova, Marina E.; Krasnokutskaya, Elena A.; Postnikov, Pavel S.; Choi, Younghwa; Chi, Ki-Whan; Filimonov, Victor D. Synthesis, 2011 , # 13 p. 2154 - 2158

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被引用次数: 17

摘要

Abstract A convenient and mild one-pot method for the synthesis of iodoarenes in high yields by the sequential diazotization-iodination of aromatic amines with a reusable polymeric diazotization agent in the presence of p-toluenesulfonic acid at room temperature in water was developed. The method is general and is the greenest alternative of the known diazotization-iodination methods. The method is also effective for the preparation of 1H- ...