Kinetics of alkaline hydrolysis and correlation studies of m-and p-substituted piperidinoethyl phenylcarbamates

M Stankovičová, J Čižmárik

文献索引：Stankovicova, Maria; Cizmarik, Jozef Collection of Czechoslovak Chemical Communications, 1989 , vol. 54, # 7 p. 1846 - 1853

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被引用次数: 1

摘要

Abstract Kinetics of alkaline hydrolysis have been studied with a series of 15 m-and p- substituted piperidinoethyl phenylcarbamates. The rate constants have been determined at 70, 60, 50, and 40 C and the activation parameters have been calculated. These values have been correlated with the substituent constants σ, F, R, F, R, π. Validity of the Hammett equation and the Swain-Lupton equation has been confirmed in the series studied and for ...