前往化源商城

Synthesis

Palladium-catalyzed silane/siloxane reductions in the one-pot conversion of nitro compounds into their amines, hydroxylamines, amides, sulfonamides, and …

RJ Rahaim Jr, RE Maleczka Jr

文献索引:Rahaim Jr., Ronald J.; Maleczka Jr., Robert E. Synthesis, 2006 , # 19 p. 3316 - 3340

全文:HTML全文

被引用次数: 29

摘要

Abstract A combination of palladium (II) acetate, aqueous potassium fluoride, and polymethylhydrosiloxane (PMHS) facilitates the room-temperature reduction of aromatic nitro compounds to anilines. These reactions tend to be quick (30 min), high-yielding, and tolerate a range of other functional groups. Replacement of PMHS/KF with triethylsilane allows for the reduction of aliphatic nitro compounds to their corresponding ...

 相关合成线路

~%

查看详情

~81%

查看详情

~97%

查看详情

~98%

查看详情

~95%

查看详情

~99%

查看详情

~99%

查看详情

~16%

查看详情

~88%

查看详情

~94%

查看详情

~52%

查看详情

~58%

查看详情

~3%

查看详情

~%

查看详情

~%

查看详情

~%

查看详情

~99%

查看详情

~99%

查看详情

~19%

查看详情

~%

查看详情

~99%

查看详情