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The Enantioselective, Organocatalyzed Diels–Alder Reaction of 2??Vinylindoles with α, β??Unsaturated Aldehydes: An Efficient Route to Functionalized …

C Zheng, Y Lu, J Zhang, X Chen, Z Chai…

文献索引:Zheng, Changwu; Lu, Yingpeng; Zhang, Junkang; Chen, Xingkuan; Chai, Zhuo; Ma, Wenying; Zhao, Gang Chemistry - A European Journal, 2010 , vol. 16, # 20 p. 5853 - 5857

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被引用次数: 85

摘要

The asymmetric, catalytic Diels–Alder reaction is one of the most powerful methods to construct functionalized, enantioenriched six-membered cyclic compounds from relatively simple substrates.[1] MacMillan and co-workers pioneered the use of organocatalysts for this reaction that features a LUMO-lowering strategy by using iminium formation.[2] Since then considerable research effort has been devoted to the development, and application, of ...