Scandium (III) trifluoromethanesulfonate catalyzed aromatic nitration with inorganic nitrates and acetic anhydride.

…, S Takeda, K Yamashita, H Abe, T Harayama

文献索引：Kawada, Atsushi; Takeda, Shigemitsu; Yamashita, Kazumi; Abe, Hitoshi; Harayama, Takashi Chemical and Pharmaceutical Bulletin, 2002 , vol. 50, # 8 p. 1060 - 1065

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被引用次数: 11

摘要

The rare earth metal (III) trifluoromethanesulfonate (rare earth metal (III) triflate, RE (OTf) 3) was found to be an efficient catalyst for aromatic nitration with carboxylic anhydride– inorganic nitrate as the nitrating agent. In the presence of a catalytic amount of RE (OTf) 3, the nitration of substituted benzenes proceeded to afford the corresponding nitrobenzenes. Especially, scandium (III) trifluoromethanesulfonate (scandium (III) triflate, Sc (OTf) 3) is ...