Palladium-catalyzed hydrocarboxylation of allenes

M Al-Masum, Y Yamamoto

文献索引：Al-Masum, Mohammad; Yamamoto, Yoshinori Journal of the American Chemical Society, 1998 , vol. 120, # 15 p. 3809 - 3810

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被引用次数: 63

摘要

The ability of transition metal complexes to activate organic molecules makes them attractive prospects for developing catalytic processes with high selectivity and high atom economy. 1 In our continuing study on hydrocarbonation, 2 hydroamination, 3and hydrosulfination4 of allenes to develop a new process for ecochemistry, we concentrated on the addition of carboxylic acids (hydrocarboxylation) to allenes. The addition of HX (X) halogen) to olefins ...