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Occurrence of electron transfer in the reduction of organic halides by lithium aluminum hydride and aluminum hydride

…, RN DePriest, AB Goel, B Wenderoth…

文献索引:Ashby, E. C.; DePriest, R. N.; Goel, A. B.; Wenderoth, Bernd; Pham, Tung N. Journal of Organic Chemistry, 1984 , vol. 49, # 19 p. 3545 - 3556

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被引用次数: 88

摘要

A variety of methods have been utilized to detect the occurrence of a single electron transfer pathway in the reduction of alkyl halides by LiAlH4 and AlH3, ie,(1) product studies of reduction of cyclizable alkyl halides containing the 5-hexenyl group,(2) trapping of intermediate radicals by dicyclohexylphosphhe and other trapping agents,(3) direct EPR observation of the trityl radical in the reduction of trityl bromide, and (4) stereochemical ...

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