前往化源商城

举例 :可输入Filippa Pettersson 或者 Cancer Res. 75(6) , 1102-12, (2015) 或者10.1002/anie.201600521

Competing radical, carbanion, and carbene pathways in the reactions of hindered primary alkyl halides with lithium dialkylamides

…, B Park, GS Patil, K Gadru, R Gurumurthy

文献索引：Ashby, E. C.; Park, B.; Patil, G. S.; Gadru, K.; Gurumurthy, R. Journal of Organic Chemistry, 1993 , vol. 58, p. 424 - 437

全文：HTML全文

被引用次数: 31

摘要

A variety of methods were utilized to study the mechanism of reaction of 6-iodo-5, 5-dimethyl- 1-hexene and its bromo, chloro, and tosylate derivatives with LDA and several other lithium dialkylamides. In the reaction of 6-iodo-5, 5-dimethyl-l-hexene with LDA in THF, radical, carbanion, and carbene pathways occurred simultaneously. However, when the corresponding bromide was allowed to react with LDA, the radical pathway was minor and ...

6-iodo-5,5-dimethylhex-1-ene结构式

6-iodo-5,5-dime...

~%

1,1,3-三甲基环戊烷结构式

1,1,3-三甲基环戊烷

3-(iodomethyl)-1,1-dimethylcyclopentane结构式

3-(iodomethyl)-...

1,1-dimethyl-3-methylidenecyclopentane结构式

1,1-dimethyl-3-...

详细

2,2-Dimethyl-5-hexenoic acid ethyl ester结构式

2,2-Dimethyl-5-...

~%

6-bromo-5,5-dimethylhex-1-ene结构式

6-bromo-5,5-dim...

2,2-二甲基-5-己烯-1-醇结构式

2,2-二甲基-5-己烯-1-醇

~80%

2,2-dimethylhex-5-enal结构式

2,2-dimethylhex...

6-bromo-5,5-dimethylhex-1-ene结构式

6-bromo-5,5-dim...

~%

1,1,3-三甲基环戊烷结构式

1,1,3-三甲基环戊烷

3-ethenyl-1,1-dimethylcyclobutane结构式

3-ethenyl-1,1-d...

1,1-dimethyl-2-(2-propenyl)cyclopropane结构式

1,1-dimethyl-2-...

详细

6-bromo-5,5-dimethylhex-1-ene结构式

6-bromo-5,5-dim...

~%

1,1,3-三甲基环戊烷结构式

1,1,3-三甲基环戊烷

3-ethenyl-1,1-dimethylcyclobutane结构式

3-ethenyl-1,1-d...

1,1-dimethyl-2-(2-propenyl)cyclopropane结构式

1,1-dimethyl-2-...

详细

6-iodo-5,5-dimethylhex-1-ene结构式

6-iodo-5,5-dime...

~%

1,1,3-三甲基环戊烷结构式

1,1,3-三甲基环戊烷

3-ethenyl-1,1-dimethylcyclobutane结构式

3-ethenyl-1,1-d...

1,1-dimethyl-2-(2-propenyl)cyclopropane结构式

1,1-dimethyl-2-...

详细

6-iodo-5,5-dimethylhex-1-ene结构式

6-iodo-5,5-dime...

~%

1,1,3-三甲基环戊烷结构式

1,1,3-三甲基环戊烷

3-ethenyl-1,1-dimethylcyclobutane结构式

3-ethenyl-1,1-d...

1,1-dimethyl-2-(2-propenyl)cyclopropane结构式

1,1-dimethyl-2-...

详细

1-chloro-2,2-dimethyl-5-hexene结构式

1-chloro-2,2-di...

~%

3-ethenyl-1,1-dimethylcyclobutane结构式

3-ethenyl-1,1-d...

1,1-dimethyl-2-(2-propenyl)cyclopropane结构式

1,1-dimethyl-2-...

未登录结构式

详细

2,2-Dimethyl-5-hexenoic acid ethyl ester结构式

2,2-Dimethyl-5-...

~%

3-ethenyl-1,1-dimethylcyclobutane结构式

3-ethenyl-1,1-d...

2,2-二甲基-5-己烯-1-醇结构式

2,2-二甲基-5-己烯-1-醇

~%

3-ethenyl-1,1-dimethylcyclobutane结构式

3-ethenyl-1,1-d...

2,2-二甲基-5-己烯-1-醇结构式

2,2-二甲基-5-己烯-1-醇

对甲苯磺酰氯(PTSC)结构式

对甲苯磺酰氯(PTSC)

~61%

2,2-dimethylhex-5-en-1-ol,4-methylbenzenesulfonic acid结构式

2,2-dimethylhex...

2,2-Dimethyl-5-hexenoic acid ethyl ester结构式

2,2-Dimethyl-5-...

~%

2,2-dimethylhex-5-en-1-ol,4-methylbenzenesulfonic acid结构式

2,2-dimethylhex...

3-(iodomethyl)-1,1-dimethylcyclopentane结构式

3-(iodomethyl)-...

~%

1,1,3-三甲基环戊烷结构式

1,1,3-三甲基环戊烷

1,1-dimethyl-3-methylidenecyclopentane结构式

1,1-dimethyl-3-...

6-iodo-5,5-dimethylhex-1-ene结构式

6-iodo-5,5-dime...

~%

5,5-Dimethyl-,(Z)-2-Hexene结构式

5,5-Dimethyl-,(...

trans-5,5-dimethyl-2-hexene结构式

trans-5,5-dimet...

1,1,3-三甲基环戊烷结构式

1,1,3-三甲基环戊烷

6-bromo-5,5-dimethylhex-1-ene结构式

6-bromo-5,5-dim...

~%

1,1,3-三甲基环戊烷结构式

1,1,3-三甲基环戊烷

3-ethenyl-1,1-dimethylcyclobutane结构式

3-ethenyl-1,1-d...

1,1-dimethyl-2-(2-propenyl)cyclopropane结构式

1,1-dimethyl-2-...

详细

6-bromo-5,5-dimethylhex-1-ene结构式

6-bromo-5,5-dim...

~%

1,1,3-三甲基环戊烷结构式

1,1,3-三甲基环戊烷

3-ethenyl-1,1-dimethylcyclobutane结构式

3-ethenyl-1,1-d...

1,1-dimethyl-2-(2-propenyl)cyclopropane结构式

1,1-dimethyl-2-...

详细

6-iodo-5,5-dimethylhex-1-ene结构式

6-iodo-5,5-dime...

~%

1,1,3-三甲基环戊烷结构式

1,1,3-三甲基环戊烷

3-(iodomethyl)-1,1-dimethylcyclopentane结构式

3-(iodomethyl)-...

1,1-dimethyl-3-methylidenecyclopentane结构式

1,1-dimethyl-3-...

详细

6-iodo-5,5-dimethylhex-1-ene结构式

6-iodo-5,5-dime...

~%

1,1,3-三甲基环戊烷结构式

1,1,3-三甲基环戊烷

3-ethenyl-1,1-dimethylcyclobutane结构式

3-ethenyl-1,1-d...

1,1-dimethyl-2-(2-propenyl)cyclopropane结构式

1,1-dimethyl-2-...

详细

6-iodo-5,5-dimethylhex-1-ene结构式

6-iodo-5,5-dime...

~%

1,1,3-三甲基环戊烷结构式

1,1,3-三甲基环戊烷

3-ethenyl-1,1-dimethylcyclobutane结构式

3-ethenyl-1,1-d...

1,1-dimethyl-2-(2-propenyl)cyclopropane结构式

1,1-dimethyl-2-...

详细

6-iodo-5,5-dimethylhex-1-ene结构式

6-iodo-5,5-dime...

~%

1,1,3-三甲基环戊烷结构式

1,1,3-三甲基环戊烷

1-(3-Butenyl)-1-methylcyclopropane结构式

1-(3-Butenyl)-1...

3-(iodomethyl)-1,1-dimethylcyclopentane结构式

3-(iodomethyl)-...

详细

6-iodo-5,5-dimethylhex-1-ene结构式

6-iodo-5,5-dime...

~%

1,1,3-三甲基环戊烷结构式

1,1,3-三甲基环戊烷

6-iodo-5,5-dimethylhex-1-ene结构式

6-iodo-5,5-dime...

~%

1,1,3-三甲基环戊烷结构式

1,1,3-三甲基环戊烷

3-ethenyl-1,1-dimethylcyclobutane结构式

3-ethenyl-1,1-d...

1,1-dimethyl-2-(2-propenyl)cyclopropane结构式

1,1-dimethyl-2-...

详细

6-iodo-5,5-dimethylhex-1-ene结构式

6-iodo-5,5-dime...

~60%

3-(iodomethyl)-1,1-dimethylcyclopentane结构式

3-(iodomethyl)-...

6-iodo-5,5-dimethylhex-1-ene结构式

6-iodo-5,5-dime...

~%

1,1,3-三甲基环戊烷结构式

1,1,3-三甲基环戊烷

3-(iodomethyl)-1,1-dimethylcyclopentane结构式

3-(iodomethyl)-...

1,1-dimethyl-3-methylidenecyclopentane结构式

1,1-dimethyl-3-...

详细

6-iodo-5,5-dimethylhex-1-ene结构式

6-iodo-5,5-dime...

~%

1,1,3-三甲基环戊烷结构式

1,1,3-三甲基环戊烷

1-(3-Butenyl)-1-methylcyclopropane结构式

1-(3-Butenyl)-1...

3-(iodomethyl)-1,1-dimethylcyclopentane结构式

3-(iodomethyl)-...

详细

2,2-Dimethyl-5-hexenoic acid ethyl ester结构式

2,2-Dimethyl-5-...

~%

3-(iodomethyl)-1,1-dimethylcyclopentane结构式

3-(iodomethyl)-...

2,2-二甲基-5-己烯-1-醇结构式

2,2-二甲基-5-己烯-1-醇

~%

3-(iodomethyl)-1,1-dimethylcyclopentane结构式

3-(iodomethyl)-...

2,2-二甲基-5-己烯-1-醇结构式

2,2-二甲基-5-己烯-1-醇

~94%

6-iodo-5,5-dimethylhex-1-ene结构式

6-iodo-5,5-dime...

3-(iodomethyl)-1,1-dimethylcyclopentane结构式

3-(iodomethyl)-...

~%

1,1,3-三甲基环戊烷结构式

1,1,3-三甲基环戊烷

1,1-dimethyl-3-methylidenecyclopentane结构式

1,1-dimethyl-3-...

6-iodo-5,5-dimethylhex-1-ene结构式

6-iodo-5,5-dime...

~%

1,1,3-三甲基环戊烷结构式

1,1,3-三甲基环戊烷

3-(iodomethyl)-1,1-dimethylcyclopentane结构式

3-(iodomethyl)-...

1,1-dimethyl-3-methylidenecyclopentane结构式

1,1-dimethyl-3-...

详细

6-iodo-5,5-dimethylhex-1-ene结构式

6-iodo-5,5-dime...

~%

1,1,3-三甲基环戊烷结构式

1,1,3-三甲基环戊烷

1-(3-Butenyl)-1-methylcyclopropane结构式

1-(3-Butenyl)-1...

3-(iodomethyl)-1,1-dimethylcyclopentane结构式

3-(iodomethyl)-...

详细

2,2-Dimethyl-5-hexenoic acid ethyl ester结构式

2,2-Dimethyl-5-...

~%

1,1-dimethyl-3-methylidenecyclopentane结构式

1,1-dimethyl-3-...

2,2-二甲基-5-己烯-1-醇结构式

2,2-二甲基-5-己烯-1-醇

~%

1,1-dimethyl-3-methylidenecyclopentane结构式

1,1-dimethyl-3-...

6-iodo-5,5-dimethylhex-1-ene结构式

6-iodo-5,5-dime...

~%

1,1-dimethyl-3-methylidenecyclopentane结构式

1,1-dimethyl-3-...

Organometallic chemistry and catalysis on gold metal surface...

[Angelici, Robert J. Journal of Organometallic Chemistry, 2008 , vol. 693, # 5 p. 847 - 856]

An efficient, scaleable procedure for the conversion of este...

[Bunnelle; Singam; Narayanan; Bradshaw; Liou Synthesis, 1997 , # 4 p. 439 - 442]

PHOTOCATALYTIC FORMATION OF SCHIFF BASES FROM PRIMARY AMINES...

[Ohtani, Bunsho; Osaki, Haruyoshi; Nishimoto, Sei-Ichi; Kagiya, Tsutomu Chemistry Letters, 1985 , p. 1075 - 1078]

Synthesis, Structure and Theoretical Studies of the Hydrido ...

[Andrikopoulos, Prokopis C.; Armstrong, David R.; Kennedy, Alan R.; Mulvey, Robert E.; O'Hara, Charles T.; Rowlings, Rene B. European Journal of Inorganic Chemistry, 2003 , # 18 p. 3354 - 3362]

PHOTOCATALYTIC FORMATION OF SCHIFF BASES FROM PRIMARY AMINES...

[Ohtani, Bunsho; Osaki, Haruyoshi; Nishimoto, Sei-Ichi; Kagiya, Tsutomu Chemistry Letters, 1985 , p. 1075 - 1078]