Journal of the American Chemical Society

Reactions involving electron transfer. VII. Use of intramolecular reactions as a test for anion radical intermediates

HO House, PD Weeks

文献索引：House,H.O.; Weeks,P.D. Journal of the American Chemical Society, 1975 , vol. 97, p. 2778 - 2785

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被引用次数: 21

摘要

Abstract: The unsaturated carbonyl compounds 9-13 have been prepared and studied as examples of enone systems 1 in which the group R is a potential intramolecular" trap" for anion radical intermediates 3. The anion radicals derived from the alkenyl enones 9-12 proved to be usually stable; consequently, use of these enones in reactions [addition of (CH&CuLi, reduction with Cr (en) z (OAc)?, reduction with Li in",(I)] thought to involve ion ...