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Journal of the Chemical Society, Perkin Transactions 1

Heteroaryl functionalised diacetylenes: preparation and solid-state reactivity

SS Talwar

文献索引:Sarkar, Abhijit; Talwar, Satya S. Journal of the Chemical Society - Perkin Transactions 1, 1998 , # 24 p. 4141 - 4146

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被引用次数: 26

摘要

Diacetylenes are known to undergo solid-state topochemical polymerisation to give polydiacetylenes. The reactivity of the monomer is controlled by the arrangement of the molecules in the crystal lattice wherein certain parametric conditions must be met for 1, 4- addition to proceed. In the present paper, we investigated the structure–reactivity relationship of a class of diacetylene monomers. Heteroaryl moieties such as thiophene, ...