Journal of the Chemical Society, Perkin Transactions 1

Heteroaryl functionalised diacetylenes: preparation and solid-state reactivity

SS Talwar

Index: Sarkar, Abhijit; Talwar, Satya S. Journal of the Chemical Society - Perkin Transactions 1, 1998 , # 24 p. 4141 - 4146

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Citation Number: 26

Abstract

Diacetylenes are known to undergo solid-state topochemical polymerisation to give polydiacetylenes. The reactivity of the monomer is controlled by the arrangement of the molecules in the crystal lattice wherein certain parametric conditions must be met for 1, 4- addition to proceed. In the present paper, we investigated the structure–reactivity relationship of a class of diacetylene monomers. Heteroaryl moieties such as thiophene, ...