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Alkylation and oxidative dimerization of enolate anions by radical chain processes

GA Russell, B Mudryk, M Jawdosiuk

文献索引:Russell, Glen A.; Mudryk, Boguslaw; Jawdosiuk, Mikolaj Journal of the American Chemical Society, 1981 , vol. 103, # 15 p. 4610 - 4611

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被引用次数: 14

摘要

SRNl. 4 In such substitutions the possibility exists that reactions 1 and 2 may merge and that Re may not be an intermediate. A distinction between a concerted process and the consecutive reactions 1 and 2 can be made on the basis of competitive experiments. When two anions are allowed to compete for a series of substrates containing a common R moiety, the relative reactivities