Atom-efficient metal-catalyzed cross-coupling reaction of indium organometallics with organic electrophiles

I Perez, JP Sestelo, LA Sarandeses

文献索引：Perez; Sestelo; Sarandeses Journal of the American Chemical Society, 2001 , vol. 123, # 18 p. 4155 - 4160

被引用次数: 209

摘要

The novel metal-catalyzed cross-coupling reaction of indium organometallics with organic electrophiles is described. Triorganoindium compounds (R3In) containing alkyl, vinyl, aryl, and alkynyl groups are efficiently prepared from the corresponding lithium or magnesium organometallics by reaction with indium trichloride. The cross-coupling reaction of R3In with aryl halides and pseudohalides (iodide 2, bromide 5, and triflate 4), vinyl triflates, benzyl ...

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