Nuclear synthons: mesyltriflone as an olefin polyanion equivalent

JB Hendrickson, GJ Boudreaux…

文献索引：Hendrickson, James B.; Boudreaux, Gerald J.; Palumbo, Paul S. Journal of the American Chemical Society, 1986 , vol. 108, # 9 p. 2358 - 2366

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被引用次数: 39

摘要

Abstract: Mesyltriflone (CF3S02CH2S02CH3) is developed as a nuclear synthon reagent capable first of multiple constructions such as alkylations then of Ramberg-Backlund elimination to a substituted olefin. The alkylations are clean and regiospecific, often amenable to one-pot operation, and in most cases the elimination is smooth. A variety of examples is presented to establish the scope of the method, and the mechanism and ...