Hydrochalcogenation of activated olefines. Synthesis of functionalized dialkylchalcogenides

JV Comasseto, RA Gariani, JL Princival…

文献索引：Comasseto, Joao V.; Gariani, Rogerio A.; Princival, Jefferson L.; Dos Santos, Alcindo A.; Zinn, Fabiano K. Journal of Organometallic Chemistry, 2008 , vol. 693, # 17 p. 2929 - 2936

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被引用次数: 17

摘要

Alkanethiols, selenols and tellurols are generated in situ by reaction of elemental sulfur, selenium and tellurium with commercial alkyllithiums, followed by reaction with deoxygenated water. The alkanechalcogenols react in situ with activated olefins in a Michael-type addition reaction.