Tetrahedron letters

Organotellurides as a source of organometallics: application in the synthesis of (+/−)-frontalin

AA Dos Santos, RS Ferrarini, JL Princival…

文献索引：Dos Santos, Alcindo A.; Ferrarini, Renan S.; Princival, Jefferson L.; Comasseto, Joao V. Tetrahedron Letters, 2006 , vol. 47, # 50 p. 8933 - 8935

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被引用次数: 22

摘要

A masked lithium homoenolate, generated by tellurium/lithium exchange, was reacted with epoxides. The lithium compound was also converted into other organometallics such as Grignard, and cuprates and the reactivity of those organometallics with epoxides was evaluated. The same building block was employed in the synthesis of (+/−)-frontalin.