Novel synthetic reactions using bis (2, 2, 2-trifluoroethoxy) triphenylphosphorane

…, S Miyashita, T Kitazume, N Ishikawa

文献索引：Kubota, Toshio; Miyashita, Satoshi; Kitazume, Tomoya; Ishikawa, Nobuo Journal of Organic Chemistry, 1980 , vol. 45, # 25 p. 5052 - 5057

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被引用次数: 35

摘要

Alkoxy-or (acyloxy)(2, 2, 2-trifluoroethoxy) triphenylphosphoranes which were prepared in situ by the ligand exchange of bis (2, 2, 2-trifluoroethoxy) triphenylphosphorane with alcohols or carboxylic acids were found to behave as potential alkylating or acylating reagents for the preparation of a variety of esters, amides, sulfides, and ketones.