Ene-diamine versus imine-amine isomeric preferences

…, BT Beckstead, JH Reibenspies…

文献索引：Reich, B. Jesse E.; Justice, Aaron K.; Beckstead, Brittany T.; Reibenspies, Joseph H.; Miller, Stephen A. Journal of Organic Chemistry, 2004 , vol. 69, # 4 p. 1357 - 1359

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被引用次数: 12

摘要

Cyanide-catalyzed aldimine coupling was employed to synthesize compounds with 1, 2-ene- diamine and α-imine-amine structural motifs: 1, 2, N, N'-tetraphenyletheylene-1, 2-diamine (13) and (±)-2, 3-di-(2-hydroxyphenyl)-1, 2-dihydroquinoxaline (17), respectively. Single- crystal X-ray diffraction provided solid-state structures and density functional theory calculations were used to probe isomeric preferences within this and the related hydroxy- ...