Inorganic Chemistry

Synergistic effects in transition-metal complexes with two or three ligands

F Strobel, DP Ridge

文献索引：Strobel, F.; Ridge, D. P. Inorganic Chemistry, 1988 , vol. 27, p. 891 - 893

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被引用次数: 18

摘要

The collision-induced decomposition spectra of several complexes ML, L2'and ML, L2L3', where M= Mn, Fe, and Co and L,= CO, NO, H20, and CH30H, are described. Treating branching ratios for ligand loss processes as equilibrium constants in these cases is justified empirically. Relative metal-ligand bond strengths derived from this treatment show antisymbiotic synergistic effects.