Crossed-beam studies of energy and angular distributions of organometallic reactions: decarbonylation of acetaldehyde by iron (I) and chromium (I)

DM Sonnenfroh, JM Farrar

文献索引：Sonnenfroh, D. M.; Farrar, J. M. Journal of the American Chemical Society, 1986 , vol. 108, # 12 p. 3521 - 3522

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被引用次数: 35

摘要

The energetics and dynamics of the reactions of gas-phase transition-metal ions with organic molecules are topics of active research and speculation at pre~ ent.~.~ In the present work, we report the first crossed-beam studies of gas-phase transition-metal ion chemistry, demonstrating that product kinetic energy and angular distributions probe the potential energy surface topology of simple carbon-carbon bond cleavage reactions. The ...