Sodium perborate: a mild and convenient reagent for efficiently oxidizing organoboranes

…, TM Shoup, NM Goudgaon

文献索引：Kabalka, George W.; Shoup, Timothy M.; Goudgaon, Naganna M. Journal of Organic Chemistry, 1989 , vol. 54, # 25 p. 5930 - 5933

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被引用次数: 135

摘要

Oxidations of organoboranes contained in THF are conveniently carried out at room temperature with sodium perborate in water. Only 1 equiv of the oxidizing agent is needed for every boron-carbon bond. Since the reagent is mildly basic (pH-9.51, the addition of external base is not required in most cases. The rate of the oxidation (12)(a) McKillop, A.; Hutchings, MG; Smith, K. Tetrahedron 1987, 43, 1753.(b) Gupton, JT; Duranceau, SJ; ...