Journal of the American Chemical Society

RESEARCHES ON ALDEHYDES. IV. THE CATALYTIC REDUCTION OF SIMPLE AND OF SUBSTITUTED CINNAMIC ALDEHYDES

MT Bogert, G Powell

文献索引：Bogert; Powell Journal of the American Chemical Society, 1931 , vol. 53, p. 2747,2752

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被引用次数: 7

摘要

,( ArCH=CRCH3 ArCHzCRHCH20H ) + HZ - ArCHzCRHCH3 In our experiments we followed the process of Skita,4 using colloidal palladium as the catalyst in most cases, since he found that with cinnamic aldehyde itself this process caused neither hydrogenation of the benzene nucleus nor formation of bimolecular compounds, under conditions similar to ours. With one mole of hydrogen per mole of cinnamic aldehyde, he reported that his product was nearly ...