… p-cyano-N, N-dimethylaniline N-oxide with metalloporphyrin salts. 2. Amine oxidation and oxygen transfer to hydrocarbon substrates accompanying the reaction of p- …

CM Dicken, FL Lu, MW Nee…

文献索引：Dicken, C. Michael; Lu, Fu-Lung; Nee, Michael W.; Bruice, Thomas C. Journal of the American Chemical Society, 1985 , vol. 107, # 20 p. 5776 - 5789

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被引用次数: 57

摘要

Abstract: The catalysis of the decomposition of p-cyano-N, N-dimethylaniline N-oxide (NO) with meso-(tetraphenylporphinato) iron (III) chloride [(TPP) Fe"'Cl] has been studied at 25 OC in CH2Cll with [Noli= 5.0 X lo4 to 8.0 XM>[(TPP) Fetl'Cl],= 3.0 X to 5.0 X lo4 M. The iron (II1) porphyrin catalyst was shown to be unaltered in catalytic efficiency to 120 turnovers (the highest examined). The influence of O2 and the purity of solvent upon the kinetics of the ...