Kinetics and Mechanisms of Oxygen Transfer in the Reaction of p-Cyano-N, N-dimethylaniline N-oxide with Metalloporphyrin Salts. 3. Catalysis by [meso-Tetrakis (2, 6 …

CM Dicken, TC Woon, TC Bruice

文献索引：Dicken, C. Michael; Woon, T. C.; Bruice, Thomas C. Journal of the American Chemical Society, 1986 , vol. 108, # 7 p. 1636 - 1643

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被引用次数: 44

摘要

Abstract: Decomposition of p-cyano-N, N-dimethylaniline N-oxide (NO) catalyzed by [meso- tetrakis (2, 6-dichlorophenyl)-porphinato] iron (III) chloride ((C1, TPP) Fe"'CI) yields as products p-cyano-N, N-dimethylaniline (DA), p-cyano-N-methylaniline (MA), and formaldehyde (CH, C12 solvent, 25" C, N, atmosphere). Intermediate in the reaction are mono and bis NO complexes (C18TPP (CI) Fe'*'N0 and CI8TPP (NO) Fe1" NO, ...