The kinetics and mechanisms of oxygen transfer in the reaction of p-cyano-N, N-dimethylaniline N-oxide with metalloporphyrin salts. 4. Catalysis by meso-[tetrakis (2, …

TC Woon, CM Dicken, TC Bruice

文献索引：Woon, T. C.; Dicken, C. Michael; Bruice, Thomas C. Journal of the American Chemical Society, 1986 , vol. 108, # 25 p. 7990 - 7995

全文：HTML全文

被引用次数: 27

摘要

Abstract: meso-(Tetrakis (2, 6-dimethylphenyl) porphinato) iron (III) chloride ((Me8TPP) Fe"'C1) is a catalyst for the conversion of p-cyano-N, N-dimethylaniline N-oxide (NO) to p- cyano-N, N-dimethylaniline (DA), p-cyano-N-methylaniline (MA), p-cyano-N-formyl-N- methylaniline (FA), p-cyanoaniline (A), N, N'-dimethyl-N, N'-bis (pcyanopheny1) hydrazine (H), N, N'-bis (p-cyanophenyl)-N-methylmethylenediamine (MD), and CH20. All evidence ...