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Convenient Synthesis of Vinyldiazomethanes from α-Diazo-β-Keto Esters and Related Systems

HML Davies, PW Hougland…

文献索引:Synthetic Communications, , vol. 22, # 7 p. 971 - 978

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被引用次数: 29

摘要

SYNTHETIC COMMUNICATIONS, 22(7), 971-978 (1992 ... ABSTRACT A series of vinydiazomethanes were readily prepared by sodium borohydride reduction of adiazo-6-ketoesters followed by phosphorus oxychloride induced dehydration of the resulting a-diazo-p-hydmxyesters ...