Convenient Synthesis of Vinyldiazomethanes from α-Diazo-β-Keto Esters and Related Systems

HML Davies, PW Hougland…

Index: Synthetic Communications, , vol. 22, # 7 p. 971 - 978

Full Text: HTML

Citation Number: 29

Abstract

SYNTHETIC COMMUNICATIONS, 22(7), 971-978 (1992 ... ABSTRACT A series of vinydiazomethanes were readily prepared by sodium borohydride reduction of adiazo-6-ketoesters followed by phosphorus oxychloride induced dehydration of the resulting a-diazo-p-hydmxyesters ...