Ti/Ni??Based Multimetallic System for the Efficient Allylation of Carbonyl Compounds

…, AG Campaña, I Rodríguez??Márquez…

文献索引：Martinez-Peragon, Angela; Millan, Alba; Campana, Araceli G.; Rodriguez-Marquez, Irene; Resa, Sandra; Miguel, Delia; Alvarez De Cienfuegos, Luis; Cuerva, Juan M. European Journal of Organic Chemistry, 2012 , # 8 p. 1499 - 1503

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被引用次数: 6

摘要

Abstract A mild method for the allylation of carbonyl compounds is presented. This methodology allows the allylation of a broad range of carbonyl compounds starting with allyl carbonates as pronucleophiles. Noteworthy is that ketones, infrequent substrates in other related protocols, are suitable substrates under these reaction conditions. Moreover, the reaction proceeds at room temperature with the use of catalytic amounts of both Ni and Ti ...