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Tetrahedron letters

Wacker oxidation of terminal olefins in a mixture of [bmim][BF 4] and water

IA Ansari, S Joyasawal, MK Gupta, JS Yadav, R Gree

文献索引:Ansari; Joyasawal, Sipak; Gupta, Manoj K.; Yadav; Gree Tetrahedron Letters, 2005 , vol. 46, # 44 p. 7507 - 7510

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被引用次数: 35

摘要

A simple and efficient PdCl2/CuCl catalyzed oxidation of alkenes has been successfully developed using a mixture of water and the ionic liquid [bmim][BF4] as solvent. Starting from various types of terminal olefins, the corresponding ketones have been prepared under mild reaction conditions and obtained in good to excellent yields after a simple extraction with diethyl ether. Furthermore, it was possible to recycle and reuse the ionic liquid and the ...

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