Canadian Journal of Chemistry

ESTER HYDRAZONES AS POSSIBLE PRECURSORS TO ALKOXYDIAZOALKANES: I. THE SYNTHESIS OF ESTER (p-TOLYLSULFONYL) HYDRAZONES AND …

RJ Crawford, R Raap

文献索引：Crawford,R.J.; Raap,R. Canadian Journal of Chemistry, 1965 , vol. 43, p. 126 - 132

被引用次数: 8

摘要

Methyl benzoate (p-tolylsulfonyl) hydrazone (I) was prepared from the reaction between (p- tolylsulfonyl) hydrazide and either methyl benzimidate hydrochloride or methyl orthobenzoate. When the potassium or sodium salt of this hydrazone was decomposed, thermally or photochemically, in the presence of alcohols, benzaldehyde mixed acetals could be isolated in good yields and of high purity. When the decomposition was carried ...

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