Methoxyphenyldiazirine as precursor to methoxyphenylcarbene

…, RA Moss, W Guo, MJ Chang

文献索引：Wlostowska, Joanna; Moss, Robert A.; Guo, Wenjeng; Chang, Ming Jing Journal of the Chemical Society, Chemical Communications, 1982 , # 8 p. 432 - 433

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被引用次数: 8

摘要

Joanna Wtostowska, Robert A. Moss," Wenjeng Guo, and Ming Jing Chang Department of Chemistry, Rutgers, The State University of New Jersey, New Brunswick, New Jersey 08903, USA ... Reaction of bromo(pheny1)diazirine (2) with methoxide ion gives methoxy(pheny1)diazirine (3), which yields cyclopropanes (4) on photolysis in alkenes. ... Methoxyphenylcarbene (1) is well known in its metal-carbene complex form. Cyclopropanations of electron-deficient ...