Canadian Journal of Chemistry

ESTER HYDRAZONES AS POSSIBLE PRECURSORS TO ALKOXYDIAZOALKANES: I. THE SYNTHESIS OF ESTER (p-TOLYLSULFONYL) HYDRAZONES AND …

RJ Crawford, R Raap

Index: Crawford,R.J.; Raap,R. Canadian Journal of Chemistry, 1965 , vol. 43, p. 126 - 132

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Citation Number: 8

Abstract

Methyl benzoate (p-tolylsulfonyl) hydrazone (I) was prepared from the reaction between (p- tolylsulfonyl) hydrazide and either methyl benzimidate hydrochloride or methyl orthobenzoate. When the potassium or sodium salt of this hydrazone was decomposed, thermally or photochemically, in the presence of alcohols, benzaldehyde mixed acetals could be isolated in good yields and of high purity. When the decomposition was carried ...

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