Studies on organosilicon chemistry. 98. Synthesis and consecutive double alkylation reactions of (2-siloxyallyl) silanes as the synthetic equivalent of acetone. alpha.,. …

…, H Hayashida, Y Tominaga

文献索引：Hosomi, Akira; Hayashida, Hisashi; Tominaga, Yoshinori Journal of Organic Chemistry, 1989 , vol. 54, # 14 p. 3254 - 3256

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被引用次数: 24

摘要

Summary:(2-Siloxyally1) silanes as the synthetic equivalent of tandem acetone apt-dianion, readily prepared by quenching of the enolate of a-(trimethylsily1) acetone with chlorosilanes or by 1, 3 C-0 Si shift of bis (organosily1)-acetone, react with various electrophiles promoted by a Lewis acid to give the corresponding a, a'-disubstituted acetones.