Preparation and Reactions of α-Halo Derivatives of Certain Tetra-substituted Hydrocarbon Silanes. Grignard Syntheses of Some Silyl Compounds1

CR Hauser, CR Hance

文献索引：Hauser; Hance Journal of the American Chemical Society, 1952 , vol. 74, p. 5091,5094,5095

全文：HTML全文

被引用次数: 90

摘要

Certain tetrasubstituted hydrocarbon silanes were chlorinated and brominated to form a- halo derivatives which were converted to silyl acetates with potassium acetate and to displacement and cleavage products with potassium cyanide and sodium amide. The Grignard reagents of a-halosilanes were condensed with acetic anhydride to form the silyl ketone, with allyl bromide to form the silyl oleh, and with acetone and benzaldehyde to ...