Preparation and Reactions of α-Halo Derivatives of Certain Tetra-substituted Hydrocarbon Silanes. Grignard Syntheses of Some Silyl Compounds1

CR Hauser, CR Hance

Index: Hauser; Hance Journal of the American Chemical Society, 1952 , vol. 74, p. 5091,5094,5095

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Citation Number: 90

Abstract

Certain tetrasubstituted hydrocarbon silanes were chlorinated and brominated to form a- halo derivatives which were converted to silyl acetates with potassium acetate and to displacement and cleavage products with potassium cyanide and sodium amide. The Grignard reagents of a-halosilanes were condensed with acetic anhydride to form the silyl ketone, with allyl bromide to form the silyl oleh, and with acetone and benzaldehyde to ...