Activation of C–H bonds in saturated hydrocarbons. H–D exchange between methane and benzene catalysed by a soluble iridium polyhydride system

CJ Cameron, H Felkin, T Fillebeen-Khan…

文献索引：Cameron, Charles J.; Felkin, Hugh; Fillebeen-Khan, Tauqir; Forrow, Nigel J.; Guittet, Eric Journal of the Chemical Society, Chemical Communications, 1986 , # 10 p. 801 - 802

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被引用次数: 17

摘要

Pioneering work by Shilov, by Garnett, and by Webster in the late 1960's and early 1970's led to the discovery that a number of soluble transition metal chlorides (notably Pt" and IF ) in acidic media are efficient catalysts for HD exchange between D20 and saturated hydrocarbons (including methane). More recently, a variety of other soluble transition metal systems have been found to activate CH bonds in alkanes via non-radical pathways.2.3 Insofar as they have been ...