Organometallics

Dialkyl (butadiene) cyclopentadienylmolybdenum (III) Complexes. Synthesis, Characterization, and Reactivity

E Le Grognec, R Poli, P Richard

文献索引：Le Grognec, Erwan; Poli, Rinaldo; Richard, Philippe Organometallics, 2000 , vol. 19, # 19 p. 3842 - 3853

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被引用次数: 10

摘要

Alkylation of 17-electron half-sandwich dichloro diene complexes of Mo (III) affords thermally stable dialkyl and mixed chloroalkyl derivatives, which are characterized by sharp isotropic EPR spectra and reversible one-electron reduction processes. They do not react with Lewis bases, while the heterolytic cleavage of the Mo-R bonds can only be accomplished by the strongest Brønsted acids.