Tetrahedron

The functionalization of saturated hydrocarbons. Part 23. Gif-type bromination and chlorination of saturated hydrocarbons: a non-radical reaction

DHR Barton, É Csuhai, D Doller

文献索引：Barton, Derek H. R.; Csuhai, Eva; Doller, Dario Tetrahedron, 1992 , vol. 48, # 42 p. 9195 - 9206

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被引用次数: 37

摘要

The bromination of saturated hydrocarbons was studied in the GoAggIII system using CBrCl3 and other polyhaloalkanes. This bromination reaction was compared to free radical processes by (i) evaluating the rates of reactions for a series of polyhaloalkanes, by (ii) measuring the selectivity of the different systems towards various saturated hydrocarbons and by (iii) analyzing the product distribution arising from the bromination of cyclohexyl ...