Tetrahedron

The functionalization of saturated hydrocarbons. Part 25. Ionic substitution reactions in GoAgg IV chemistry: the formation of carbon-halogen bonds

DHR Barton, SD Bévière, W Chavasiri

文献索引：Barton, Derek H. R.; Beviere, Stephane D.; Chavasiri, Warinthorn Tetrahedron, 1994 , vol. 50, # 1 p. 31 - 46

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被引用次数: 20

摘要

GoAggIV chemistry (Fe (III) species, tert-butyl hydroperoxide in a mixture of pyridine and acetic acid) in the presence of LiCl can transform saturated hydrocarbons efficiently into the corresponding alkyl chlorides. The transformation into monosubstituted alkyl derivatives by “ionic trapping” reagents arising from the interception of the first intermediate of the system supports the presence of a high valent VFe-C species. Mechanistic studies suggest a ...