Lithium in ammonia reduction of 3-ethoxycyclohexenone

DS Watt, JM McKenna, TA Spencer

文献索引：Watt,D.S. et al. Journal of Organic Chemistry, 1967 , vol. 32, p. 2674 - 2678

全文：HTML全文

被引用次数: 8

摘要

The composition of the product mixture from the reduction of 3-ethoxycyclohexenone (1) by lithium in ammonia under a variety of conditions has been determined. By appropriate choice of conditions, the predominant product can be made any of four compounds: cyclohexanone (2), cyclohexanol (J), 3-ethoxycyclohexanone (4), or cis-3- ethoxycyclohexanol (5). At-7S0, products formed via elimination of ethoxide from enolate ...