Homolytic decomposition of t-alkyl 2, 2-dimethylperoxypropionates

T Komai, K Matsuyama, M Matsushima

文献索引：Komai, Takeshi; Matsuyama, Kazuo; Matsushima, Masaru Bulletin of the Chemical Society of Japan, 1988 , vol. 61, # 5 p. 1641 - 1646

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被引用次数: 13

摘要

Decomposition rates and products of t-alkyl 2, 2-dimethylperoxypropionates were measured in cumene at several temperatures. The peroxyesters decomposed homolytically, depending on the structure of the t-alkyl moiety. The relative rates of the t-alkyl moieties to the 1, 1-dimethylethyl one were: 1, 1-dimethylbutyl (1.14), 1, 1-dimethylpropyl (1.19), 1, 1, 2- trimethylpropyl (1.85), 1, 1, 3, 3-tetramethylbutyl (2.10), and 1, 1-dimethyl-2-phenylethyl ( ...