Heterometallic CoIII4FeIII2 Schiff Base Complex: Structure, Electron Paramagnetic Resonance, and Alkane Oxidation Catalytic Activity

…, VV Bon, R Boča, YN Kozlov, LS Shul'pina…

文献索引：Shul'pin, Georgiy B.; Golfeto, Camilla C.; Suess-Fink, Georg; Shul'pina, Lidia S.; Mandelli, Dalmo Tetrahedron Letters, 2005 , vol. 46, # 27 p. 4563 - 4567

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被引用次数: 61

摘要

We have found that a novel heterometallic Co/Fe Schiff base complex possesses a number of unique features, among them an outstanding activity toward oxidation of hydrocarbons with H2O2, under mild conditions: a TON of 3.6× 103, yield of 46%, and TOF of 1.12× 104 h−