Journal of the American Chemical Society

Unsaturated Chlorosilanes

RE Scott, KC Frisch

文献索引：Scott; Frisch Journal of the American Chemical Society, 1951 , vol. 73, p. 2599

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被引用次数: 32

摘要

Aryl and alkaryl unsatur6ted chlorosilanes as well as dialkenyl chlorosilanes, containing different alkenyl groups, were prepared conveniently by means of the Grignard reaction and characterized. Seven new unsaturated chlorosilanes of this type were thus prepared. Triallylchlorosilane was prepared for the first time in pure state and its structure confirmed by the conversion into the corresponding ethoxy derivative. The molar refractions of these ...