Journal of the American Chemical Society

Unsaturated Chlorosilanes

RE Scott, KC Frisch

Index: Scott; Frisch Journal of the American Chemical Society, 1951 , vol. 73, p. 2599

Full Text: HTML

Citation Number: 32

Abstract

Aryl and alkaryl unsatur6ted chlorosilanes as well as dialkenyl chlorosilanes, containing different alkenyl groups, were prepared conveniently by means of the Grignard reaction and characterized. Seven new unsaturated chlorosilanes of this type were thus prepared. Triallylchlorosilane was prepared for the first time in pure state and its structure confirmed by the conversion into the corresponding ethoxy derivative. The molar refractions of these ...