The stereochemistry of the cyclic β-halogeno-ether synthesis of olefinic alcohols

L Crombie, RD Wyvill

文献索引：Crombie, Leslie; Wyvill, Robert D. Journal of the Chemical Society, Chemical Communications, 1984 , # 16 p. 1056 - 1058

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摘要

The Stereochemistry of the Cyclic P-Halogeno-ether Synthesis of Olefinic Alcohols ... Leslie Crombie" and Robert D. Wyvill Department of Chemistry, The University, Nottingham NG7 ZRD, UK ... The (a/(€) composition of olefinic alcohols produced by sodium ring-scission of cyclic P-halogeno-ethers can be accounted for by a mechanism involving fast electron transfer and carbanion inversion, with ring-cleavage speedier than conformationa I inversion.