Tetrahedron letters

Synthesis of E-homoallylic alcohols, γ-hydroxyketones, and cyclopropyl ketones from 3-diphenylphosphinoyl (Ph2PO) propanols by acyl transfer

P Wallace, S Warren

文献索引：Wallace, Paul; Warren, Stuart Tetrahedron Letters, 1985 , vol. 26, # 46 p. 5713 - 5716

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被引用次数: 12

摘要

Carboxyl transfer (O→C) on 3-Ph 2 PO propyl esters (9) gives an intermediate (10) from which the Ph 2 PO group may be removed by the Horner-Wittig reaction or by Ph 2 PO transfer (C→O) to give the title compounds. ... Org. React., 8 (1954), pp. 59–196 see pp 90-95 and table XVI 168.