Enantiodivergent and γ??Selective Asymmetric Allylic Amination

J Wang, J Chen, CW Kee…

文献索引：Wang, Jianmin; Chen, Jie; Kee, Choon Wee; Tan, Choon-Hong Angewandte Chemie - International Edition, 2012 , vol. 51, # 10 p. 2382 - 2386

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被引用次数: 39

摘要

There are many readily available methods for the preparation of enantiopure carbonyl compounds containing a-and bchiral centers. However, the selective functionalization of the g position has been met with more difficulties and less progress. Asymmetric vinylogous aldol reactions,[1] Michael [2] reactions, and phosphine-catalyzed nucleophilic addition to alkynes and allenes [Eq.(1)][3] are some of the successful attempts made to address this ...