Laser-powered homogeneous pyrolysis of 1, 1-dimethyl-1-silacyclobutane in the presence of some common monomers

…, D Čukanová, M Minárik, A Lyčka, J Tláskal

文献索引：Pola, Josef; Cukanova, Dana; Minarik, Milan; Lycka, Antonin; Tlaskal, Jaroslav Journal of Organometallic Chemistry, 1992 , vol. 426, # 1 p. 23 - 34

全文：HTML全文

被引用次数: 17

摘要

Abstract Laser-induced homogeneous pyrolysis of 1, 1-dimethyl-1-silacyclobutane yields 1, 1, 3, 3-tetramethyl-1, 3-disilacyclobutane and ethene as major products. In the presence of vinyl acetate, allyl methyl ether, acrolein, methyl vinyl ether, methyl acrylate or methyl methacrylate, the intermediate dimethylsilene is trapped by these monomers, or by products of their thermal decomposition, to yield both volatile and viscous or solid organosilicon ...