Pyrolytic, kinetic, and theoretical studies on the isomerization of Me2HSiCH2. bul. to Me3Si. bul.

TJ Barton, A Revis, IMT Davidson…

文献索引：Barton,T.J.; Revis,A.; Davidson,I.M. Journal of the American Chemical Society, 1986 , vol. 108, p. 4022

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被引用次数: 13

摘要

Conclusions The effects of NH, binding to the 02-evolving complex are consistent with coordination of one or more NH3 molecules directly to the Mn site detectable in the S2 state by EPR spectroscopy. The novel S2 state EPR spectrum produced in the presence of NH4Cl with illumination at 0" C shows a near-Curie law temperature dependence which is significantly different from the temperature dependence of S2 state EPR signals observed ...